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Monitoring Biogas with Electrochemical Gas Sensors

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What is Biogas Detection with Electrochemical Gas Sensors?

Biogas, a renewable energy source, is produced through the anaerobic digestion of organic matter. It typically consists of methane (CH₄), carbon dioxide (CO₂), trace gases such as hydrogen sulfide (H₂S), and water vapor. Accurate monitoring of biogas composition is essential for ensuring efficient energy recovery, operational safety, and environmental compliance. Solid polymer electrochemical gas sensors (SPEGS) are highly effective in biogas monitoring due to their sensitivity, selectivity, and robust performance in challenging environments.

What are typical Applications for Biogas Monitoring?

  • Process Optimization:
    • Excessive H₂S levels can damage equipment and reduce the efficiency of biogas upgrading systems.
  • Safety Assurance:
    • H₂S is toxic and corrosive, necessitating accurate detection to protect personnel and infrastructure.
  • Environmental Compliance:
    • Monitoring ensures adherence to emission regulations, reducing the environmental impact of biogas production.
  • Leak Detection and Safety Monitoring:
    • Portable SPEGS can be deployed to detect leaks, reducing fire and explosion hazards.

Advantages of Solid Polymer Electrochemical Gas Sensors for Biogas Applications

  • Long Lifetime
    • Solid polymer electrochemical sensors are designed to provide consistent and reliable performance over extended periods, reducing maintenance and replacement costs.
  • High Selectivity and Sensitivity:
    • SPEGS are highly selective, enabling accurate detection of specific gases such as H₂S, NH3, O2 and CO even in mixed gas environments.
  • Robustness in Harsh Conditions:
    • These sensors are resistant to high humidity and temperature variations commonly found in biogas production sites.
  • Compact and Low-Power Design:
    • SPEGS are lightweight and energy-efficient, ideal for integration into portable and remote monitoring systems.
  • Fast Response Time:
    • The rapid response of SPEGS allows real-time monitoring of gas concentration changes, enabling timely interventions.

Which Gases need to be monitored in Biogas Applications?

  • Hydrogen Sulfide (H₂S)
    • Why measure?
      • H₂S is a toxic and corrosive gas present in trace amounts (typically 0.1–1%).
      • It can damage equipment like engines, pipelines, and gas upgrading systems if not properly removed.
    • Measurement Goal:
      • Prevent corrosion and ensure compliance with occupational safety limits.
  • Oxygen (O₂)
    • Why measure?
      • Oxygen can indicate air ingress into the system, which could lead to process inefficiencies and safety risks such as explosion hazards.
      • Anaerobic digestion requires oxygen-free conditions to function effectively.
    • Measurement Goal:
      • Detect leaks or malfunctions in the system to maintain proper anaerobic conditions.
  • Ammonia (NH₃)
    • Why measure?
      • Ammonia can form as a byproduct of protein degradation in feedstock.
      • High ammonia levels can inhibit microbial activity, reducing methane production.
    • Measurement Goal:
      • Monitor ammonia levels to protect the digestion process and maintain biogas quality.
  • Trace Gases (e.g., Carbon Monoxide – CO)
    • Why measure?
      • Trace gases like carbon monoxide may be present in certain feedstocks or post-combustion processes.
      • While not typically a concern in raw biogas, trace gases may be monitored in downstream applications.
    • Measurement Goal:
      • Assess any impurities that could affect the end-use of biogas.
Summary of Key Gases and Their Importance:
Properly monitoring these gases ensures that biogas production is efficient, safe, and environmentally sustainable.

What are the Advantages of EC Sense Biogas Gas Sensor Products?

  • General Features:
    • Lower detectable limit of 1 ppb / 1 µg/m³
    • Fast response time
  • Gas Sensor Features:
    • Small size
    • Long lifetime > 3 years
    • No warm-up time required
    • No zero line drift
  • Gas Sensor Module Features:
    • Detects gas, temperature and humidity
    • Digital signal UART (TTL 3.3 V) or I2C output
    • Low power consumption and sleep mode (suitable for battery and IoT applications)
    • Wide temperature range of -40 °C to +55 °C

Which Solutions can EC Sense offer for Biogas Applications?

Which Technology makes EC Sense Sensors special?

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The EC Sense solid polymer electrochemical technology is a revolutionary innovation in the field of electrochemical detection. This technology is based on the principle of electrochemical catalytic reaction, detecting the output signals of the electrochemical reactions of different gases and accurately measuring the gas concentration through the signal. The sensor is composed of three electrodes in contact with the electrolyte. A typical electrode consists of a large surface area of noble metal and other materials. The electrode, electrolyte and the surrounding air are in contact and the gas diffuses into the working electrode. Here the gas will be oxidized, this causes a current, which is proportional to the gas concentration.

Solid polymer electrochemical gas sensors are a valuable tool for monitoring and managing biogas production processes. Their precision, durability, and adaptability make them an excellent choice for enhancing efficiency, ensuring safety, and meeting regulatory requirements. With proper implementation, these sensors enable a more sustainable and economically viable approach to renewable energy generation.

Monitoring Biogas with Electrochemical Gas Sensors

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Controlling the Air Quality inside and outside of animal farms is important for the health of the animals, the health of the farm workers, for the surrounding neighborhood and environment and finally for the quality of our food and therefore also for the health of the end consumer.
Therefore, EC Sense has developed a reliable Long Life Ammonia Sensor Device, ECtox, which can measure continuously high background ammonia gas concentrations in the air.
Why is Air Quality for Animals important?

The meat consumption has risen steadily in recent years. There is already a large industry that breeds such “meat” at top speed.
A chicken’s life is only 8 weeks long. A pig’s life on a small farm is about a year long; in an industrial farm it is only 120 days. In order to maximize profit, the population in an industrial animal breeding facility is constantly raised. This increases the risk that this population will be affected by diseases.

What is the Cause of the Pollution?

The pollution is caused by the respiration of the animals and by the digestion of the food. Humidity increases due to the high population and because the waste remains in place for a while. Many methane gases are produced during digestion of green fodder. NH3 and H2S are toxic gases and harm animals in higher concentrations.

To optimize cultivation and make the shelf life of our future food acceptable, the following air quality basics should be observed:
1. Temperature and Humidity: Humidities above 70% r.H. and temperatures below 10°C or above 30°C stress our future food.
2. Odors generated by the waste of the animals: Same as us humans, animals produce CO2. However, the animal waste falls to the ground and produces CO2 in the air. Due to a high animal density, the concentration inside a barn is higher than outside. High CO2 levels make the animals tired and weak, sometimes even aggressive. Farmers have to add drugs to the diet to control the situation.
Good air quality would reduce these problems to a minimum.

Pig Farms

Typically, the concentration in a piggery should be below 10ppm. At this level, the pigs remain healthy.
At concentrations above 20ppm NH3, the pigs’ health becomes unstable. The following health risks may occur:
a. Lung infection
b. Heart and cardiac system problems
c. Aggressive behavior, tails and ears are bitten off.
The animals’ health degrades faster, infecting others and not growing as quickly and successfully.
To counteract these problems, the following activities have to happen:
a. Animal wastes are mainly NH3 ammonia, sulfide, amines. Keep this level at least below 15ppm.
b. Measure the NH3 concentration with the ECtox, the only long-life Gas Sensor available at the moment.
c. In case the values are too high air exchange is required.
High NH3 concentrations leaving the piggery will also enter the neighborhood. The gas should be cleaned up before it leaves the stall area. Ozone would be a good cleaning agent for this application.

Chickens, Ducks and Cows

However, the concentration level which affects the animals is in different ranges. As chickens are smaller, they are also affected by smaller ammonia concentrations. The controlled level should be around 5ppm. Only at this level the growth runs at full speed and less medicine is needed to stabilize the animals’ health.

ECtox - Long Life NH3 Sensor Device

Our NH3 Gas Sensor, like any other Gas Sensor on the market, also has problems with continuous background concentrations, whose lifetime quickly deteriorates due to the continuously high ammonia concentrations in the environment. The reason for this is a drift of the zero line over time.
Therefore, EC Sense created an instrument to counteract this common problem in animal husbandry gas sensing.
The ECtox has a free zero line. The technology to detect NH3 is called coulometry. This type of detection does not require calibration because the NH3 is analysed each time it is detected.

Advantages of the ECtox:

  • Long Lifetime
  • Humidity Resistance
  • Anti-Interference
  • Poison Resistance
  • Detects Single Gas + Temp. + Humidity
  • Water and Dust Proof
  • Automatic Scaling from 1 to 500ppm NH3
  • Fully Compensated Digital Output
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